multinuclear variable temperature nmr studies on cyanide, water and hydroxyl group scrambling on halogenation of k2[pt(cn)4] and related reactions
نویسندگان
چکیده
195pt and 1h nmr has been used to show that addition of chlorine and bromine to [pt(cn)4]2_ in presence of perchloric acid in water results in cyanide and water scrambling with formation of eleven complexes of the type [pt(cn)4-ncl(h2o)n+1](n-1)+ (n=0, 1, 2, 3, 4). addition of nbu4oh to this solution gives (nbu4)2[pt(cn)4cl(oh)]. nmr measurements in acetone also show cyanide and hydroxyl group scrambling with formation of complexes of the type [pt(cn)4-ncl(oh)n+1]2-, (n=0, 1, 2, 3, 4).
منابع مشابه
Multinuclear Variable Temperature NMR Studies on Cyanide, Water and Hydroxyl Group Scrambling on Halogenation of K2[Pt(CN)4] and Related Reactions
195Pt and 1H NMR has been used to show that addition of chlorine and bromine to [Pt(CN)4]2_ in presence of perchloric acid in water results in cyanide and water scrambling with formation of eleven complexes of the type [Pt(CN)4-nCl(H2O)n+1](n-1)+ (n=0, 1, 2, 3, 4). Addition of NBu4OH ...
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 17
شماره 2 1998
کلمات کلیدی
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